- Conduction refers to the transport of energy in a medium (solid, liquid or gas) due to a temperature gradient.
- The physical mechanism is random atomic or molecular activity
- Governed by Fourier’s law
In this chapter we will learn
- The definition of important transport properties and what governs thermal conductivity in solids, liquids and gases
- The general formulation of Fourier’s law, applicable to any geometry and multiple dimensions
- How to obtain temperature distributions by using the heat diffusion equation.
- How to apply boundary and initial conditions
Thermal Properties of Matter
Recall from Chapter 1, equation for heat conduction:
The proportionality constant is a transport property, known as thermal conductivity k
•Usually assumed to be isotropic (independent of the direction of transfer): kx=ky=kz=k
Thermal Conductivity: SolidsThermal Conductivity: Solids
•Solid comprised of free electrons and atoms bound in lattice
•Thermal energy transported through
- Migration of free electrons, ke
- Lattice vibrational waves, kl- Intermolecular spacing is much larger
- Molecular motion is random
- Thermal energy transport less effective than in solids; thermal conductivity is lower
where n the number of particles per unit volume, the mean molecular speed and l the mean free path (average distance travelled before a collision)
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